كربوران: الفرق بين النسختين

[نسخة منشورة][نسخة منشورة]
تم حذف المحتوى تمت إضافة المحتوى
مقالات B
 
ط تعديل وصلة
سطر 12:
من أكثر مركبات الكربورانات دراسة مركب اثنا عشري البوران ثنائي الكربون C<sub>2</sub>B<sub>10</sub>H<sub>12</sub>، والذي حضر لأول مرة سنة 1963.<ref>{{cite journal | author = Heying, T. L.; Ager, J. W.; Clark, S. L.; Mangold, D. J.; Goldstein, H. L.; Hillman, M.; Polak, R. J.; Szymanski, J. W. | title = A New Series of Organoboranes. I. Carboranes from the Reaction of Decaborane with Acetylenic Compounds | journal = Inorganic Chemistry | year = 1963 | volume = 2 | issue = 6 | pages = 1089–1092 | doi = 10.1021/ic50010a002 }}{{cite journal | author = Schroeder, H.; Heying, T. L.; Reiner, J. R. | title = A New Series of Organoboranes. II. The Chlorination of 1,2-Dicarbaclosododecaborane(12) | journal = Inorganic Chemistry | year = 1963 | volume = 2 | issue = 6 | pages = 1092–1096 | doi = 10.1021/ic50010a003 }}{{cite journal | author = Heying, T. L.; Ager, J. W.; Clark, S. L.; Alexander, R. P.; Papetti, S.; Reid, J. A.; Trotz, S. I. | title = A New Series of Organoboranes. III. Some Reactions of 1,2-Dicarbaclosododecaborane(12) and its Derivatives | journal = Inorganic Chemistry | year = 1963 | volume = 2 | issue = 6 | pages = 1097–1105 | doi = 10.1021/ic50010a004 }}{{cite journal | author = Papetti, S.; Heying, T. L. | title = A New Series of Organoboranes. IV. The Participation of the 1,2-Dicarbaclosododecaborane(12) Nucleus in Some Novel Heteratomic Ring Systems | journal = Inorganic Chemistry | year = 1963 | volume = 2 | issue = 6 | pages = 1105–1107 | doi = 10.1021/ic50010a005 }}{{cite journal | author = Fein, M. M.; Bobinski, J.; Mayes, N.; Schwartz, N.; Cohen, M. S. | title = Carboranes. I. The Preparation and Chemistry of 1-Isopropenylcarborane and its Derivatives (a New Family of Stable Closoboranes) | journal = Inorganic Chemistry | year = 1963 | volume = 2 | issue = 6 | pages = 1111–1115 | doi = 10.1021/ic50010a007 }}{{cite journal | author = Fein, M. M.; Grafstein, D.; Paustian, J. E.; Bobinski, J.; Lichstein, B. M.; Mayes, N.; Schwartz, N. N.; Cohen, M. S. | title = Carboranes. II. The Preparation of 1- and 1,2-Substituted Carboranes | journal = Inorganic Chemistry | year = 1963 | volume = 2 | issue = 6 | pages = 1115–1119 | doi = 10.1021/ic50010a008 }}{{cite journal | author = Grafstein, D.; Bobinski, J.; Dvorak, J.; Smith, H.; Schwartz, N.; Cohen, M. S.; Fein, M. M. | title = Carboranes. III. Reactions of the Carboranes | journal = Inorganic Chemistry | year = 1963 | volume = 2 | issue = 6 | pages = 1120–1125 | doi = 10.1021/ic50010a009 }}{{cite journal | author = Grafstein, D.; Bobinski, J.; Dvorak, J.; Paustian, J. E.; Smith, H. F.; Karlan, S.; Vogel, C.; Fein, M. M. | title = Carboranes. IV. Chemistry of Bis-(1-carboranylalkyl) Ethers | journal = Inorganic Chemistry | year = 1963 | volume = 2 | issue = 6 | pages = 1125–1128 | doi = 10.1021/ic50010a010 }}{{cite journal | author = Grafstein, D.; Dvorak, J. | title = Neocarboranes, a New Family of Stable Organoboranes Isomeric with the Carboranes | journal = Inorganic Chemistry | year = 1963 | volume = 2 | issue = 6 | pages = 1128–1133 | doi = 10.1021/ic50010a011 }}</ref>
 
يحضر من تفاعل [[أسيتيلين|الأسيتيلين]] مع [[عشاري البوران]]. يمكن إجراء تعديل لهذه الطريقة باستعمال [[ثنائي ميثيل ثمتئيثنائي كربوكسيلات الأسيتيلين]] DMAD ليعطي C<sub>2</sub>B<sub>10</sub>H<sub>10</sub>(CO<sub>2</sub>C H<sub>3</sub>)<sub>2</sub>، والذي يمكن أن يحوّل إلى C<sub>2</sub>B<sub>10</sub>H<sub>12</sub>.<ref>{{cite journal | author = Kutal, C. R.; Owen, D. A.; Todd, L. J. | title = Closo-1,2-dicarbadodecaborane(12) | journal = Inorganic Syntheses | year = 1968 | volume = 11 | pages = 19–23 | doi = 10.1002/9780470132425.ch5 | isbn = 978-0-470-13242-5 }}</ref>
 
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